Metal-catalysis in Industrial Organic Processes
نویسندگان
چکیده
منابع مشابه
Biomimetic catalysis of metal-organic frameworks.
Metal-organic frameworks (MOFs) have attracted great attention as a new type of prospective material with various merits and functionalities. MOFs can either act as biomimetic catalysts to mimic enzymatic activities or serve as hosts to encapsulate bio-active species for biomimetic catalysis. However, in comparison with the dramatic development of MOFs in other catalytic fields, MOF-based biomi...
متن کاملHomochiral metal-organic frameworks for heterogeneous asymmetric catalysis.
Homochiral crystallizations of two enantiomeric metal-organic frameworks (MOFs) Ce-MDIP1 and Ce-MDIP2 were achieved by using L- or D-BCIP as chiral inductions, respectively, where the chiralities were characterized by solid state CD spectra. Ce-MDIPs exhibit excellent catalytic activity and high enantioselectivity for the asymmetric cyanosilylation of aromatic aldehydes; the homochiral Cd-TBT M...
متن کاملAccelerated Computational Analysis of Metal−Organic Frameworks for Oxidation Catalysis
High-spin iron(IV)−oxo compounds are known to activate strong C−H bonds. Stabilizing the high-spin S = 2 electronic configuration is difficult in molecular species for homogeneous catalysis, but recent experimental and computational results suggest this can be achieved in the metal−organic framework Fe2(dobdc) (dobdc 4− = 2,5-dioxido-1,4-benzenedicarboxylate) and its magnesium-diluted analogues...
متن کاملComputational Design of Functionalized Metal–Organic Framework Nodes for Catalysis
Recent progress in the synthesis and characterization of metal-organic frameworks (MOFs) has opened the door to an increasing number of possible catalytic applications. The great versatility of MOFs creates a large chemical space, whose thorough experimental examination becomes practically impossible. Therefore, computational modeling is a key tool to support, rationalize, and guide experimenta...
متن کاملReusable oxidation catalysis using metal-monocatecholato species in a robust metal-organic framework.
An isolated metal-monocatecholato moiety has been achieved in a highly robust metal-organic framework (MOF) by two fundamentally different postsynthetic strategies: postsynthetic deprotection (PSD) and postsynthetic exchange (PSE). Compared with PSD, PSE proved to be a more facile and efficient functionalization approach to access MOFs that could not be directly synthesized under solvothermal c...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Synthesis
سال: 2007
ISSN: 0039-7881,1437-210X
DOI: 10.1055/s-2007-984732